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- PublicationMétadonnées seulement1,1'-Disubstituted ferrocene-containing thermotropic liquid crystals of structure [Fe{(?5-C5H4)COOC6H4XC6H4OCnH2n+1}2] (X = OOC or COO). Influence of the orientation of the central ester function on the mesogenic properties(1993)
; - PublicationMétadonnées seulement1,3-Disubstituted ferrocene-containing thermotropic liquid crystals: synthesis, mesomorphic properties and the crystal and molecular structure(1993)
; - PublicationMétadonnées seulement1,4-Bis(hexyloxy)-2,5-diiodobenzene(2010)
; ; - PublicationMétadonnées seulement1,4-Bis[4-(tert-butyldiphenylsilyl)buta-1,3-diynyl]benzene(2010)
; ; The title centrosym. mol., C46H42Si2, is composed of a central benzene ring with buta-1,3-diynyl chains at positions 1 and 4. These chains are terminated by tert-butyldiphenylsilyl groups, hence the mol. is dumbbell in shape. The mols. are connected via C-H...? interactions in the structure, so forming an undulating 2D network in the bc plane. There is also a weak ?-? interaction involving centrosym. related Ph rings with a centroid-centroid distance of 3.8359(11) Å. Crystal data: monoclinic, P21/c, a = 8.535(1), b = 17.2060(14), c = 13.4923(14) Å, ? = 104.064(9)°, Z = 2, 3260 obsd. reflections with I > 2(I), 220 refined parameters, R[F2 > 2?(F2)] = 0.044, wR(F2) = 0.104. [on SciFinder(R)] - PublicationMétadonnées seulement100 GHz passively mode-locked Er: Yb: glass laser at 1.5 ?m with 1.6-ps pulses(2008)
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- PublicationAccès libre10th International Conference on Innovative Internet Community Services (I2CS)(Bonn: GI-Edition, 2010)
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- PublicationMétadonnées seulement16.2-W average power from a diode-pumped femtosecond Yb: YAG thin disk laser(2000)
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- PublicationMétadonnées seulement2,2'-(Propane-2,2-di-yl)bis-(1H-pyrrole)The title compound, C(11)H(14)N(2), crystallized with two independent mol-ecules (A and B) in the asymmetric unit. The two mol-ecules differ only slightly, with the pyrrole rings being inclined to one another at a dihedral angle of 87.67 (8)° in mol-ecule A and 88.09 (7)° in mol-ecule B. In the crystal, there are no classical hydrogen bonds, but the two pyrrole NH groups of one mol-ecule are involved in N-H(midline ellipsis)? inter-actions with the pyrrole rings of the other mol-ecule. In this manner, a compact box-like arrangement of the two independent mol-ecules is formed.
- PublicationMétadonnées seulement2,2'-(Propane-2,2-diyl)bis(1H-pyrrole)2,2'-(Propane-2,2-diyl)bis(1H-pyrrole), C11H14N2, crystd. with 2 independent mols. (A and B) in the asym. unit. The 2 mols. differ only slightly, with the pyrrole rings being inclined to 1 another at a dihedral angle of 87.67(8)° in mol. A and 88.09(7)° in mol. B. In the crystal, there are no classical H bonds, but the 2 pyrrole NH groups of 1 mol. are involved in N-H···? interactions with the pyrrole rings of the other mol. In this manner, a compact box-like arrangement of the 2 independent mols. is formed. Crystallog. data are given. [on SciFinder(R)]
- PublicationMétadonnées seulement2,3,4,7-Tetrahydro-1H-inden-2-ol: synthesis, molecular structure and coordination chemistry(2004)
; 2,3,4,7-Tetrahydro-1H-inden-2-ol (1) has been synthesized by Birch redn. of indan-2-ol. A single-crystal x-ray structure anal. of 1 shows the compd. to exist as hydrogen-bonded polymers along the c-axis due to the presence of a series of hydrogen-bonds between hydroxo functions. The ferrocene ester derivs., ferrocene carboxylic acid 2,3,4,7-tetrahydro-1H-inden-2-yl ester (2) and ferrocene carboxylic acid indan-2-yl ester (3) have been prepd. by peptidic coupling of ferrocene carboxylic acid with 1 and with indan-2-ol, resp. The single-crystal x-ray structure anal. of 2 and 3 reveal in both cases the cyclopentadienyl rings to adopt an eclipsed conformation with the indenyl substituent being rotated out of the Cp ester plane by almost 90°, allowing no efficient interaction between the ?-system of the Cp ring and the indene moiety. The dienyl deriv. 2 reacts with RuCl3 · nH2O in refluxing ethanol to afford [Ru(arene)Cl2]2 (4) (arene = ferrocene carboxylic acid indan-2-yl ester) as a mixt. of isomers. [on SciFinder(R)] - PublicationMétadonnées seulement[2,6-Bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine-?3N]trichlororhodium(III) monohydrate(2003)
; Crystals of the title compd. are monoclinic, space group C2/c, with a 18.682(4), b 14.821(3), c 14.819(3) Å, ? 126.57(3)°; Z = 8, dc = 1.776; R = 0.036, Rw(F2) = 0.079 for 3136 reflections. The mononuclear octahedral Rh(III) complex shows a H bond between the equatorial Cl atom and the solvent H2O mol. [on SciFinder(R)] - PublicationMétadonnées seulement[2,6-Bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine]trichlororhodium(III) dibenzene solvate(2002)
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