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Highly Fluorescent Liquid-Crystalline Dendrimers Based on Borondipyrromethene Dyes
Auteur(s)
Date de parution
2009
In
Chemistry of Materials, American Chemical Society (ACS), 2009/21/17/3950–3959
Résumé
Fluorescent mesomorphic materials have been synthesized by grafting difluoro-bora-diaza-<i>s</i>-indacene (<i>F</i>-Bodipy) onto first-, second-, and third-generation liquid-crystalline poly(aryl ester) dendrons functionalized with cyanobiphenyl units. The second- and third-generation dendrimers give rise to smectic A phases; the first-generation dendrimer shows a nematic phase and an unidentified phase. The supramolecular organization within the smectic A phase could be established from X-ray experiments: the dendritic core is oriented approximately parallel to the layer planes and the mesogenic units are oriented perpendicularly above and below the dendritic core; interdigitation occurs between neighboring layers. All the materials are highly fluorescent both in solution and in the mesophases. For the first-generation dendrimer, the formation of <i>J</i>-aggregates was detected. The higher-generation dendrons prevented the formation of aggregates. Therefore, the dendrons play the role of liquid-crystalline promoters and protective shells.
Identifiants
Type de publication
journal article
