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Highly Efficient NMR Enantiodiscrimination of Chiral Octanuclear Metalla-Boxes in Polar Solvent
Auteur(s)
Date de parution
2009
In
Organometallics, American Chemical Society (ACS), 2009/28/16/4894–4897
Résumé
Detection of the molecular chirality of a series of octanuclear metalla-boxes can be readily achieved using the NMR chiral solvating agent Λ-BINPHAT in CD<sub>3</sub>CN: only 0.05 to 0.10 equiv being necessary for a complete baseline separation of some of the proton signals.
Identifiants
Type de publication
journal article
