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Carboxylation of methane with CO or CO<sub>2</sub> in aqueous solution catalysed by vanadium complexes

Auteur(s)
Nizova, Galina V.
Stanislas, Sandrine
Shulpin, Georgiy B.
Date Issued
1998
Journal
Chemical Communications, 1998//1885-1886
Abstract
Reaction of methane with CO or CO<sub>2</sub> in aqueous solution in the presence of O<sub>2</sub> (catalysed by NaVO<sub>3</sub>) or H<sub>2</sub>O<sub>2</sub> (catalysed by NaVO<sub>3</sub>–pyrazine-2-carboxylic acid) at 25–100 °C affords acetic acid and in some cases also methanol, methyl hydroperoxide and formaldehyde.
Identifiers
https://libra.unine.ch/handle/123456789/18787
_
10.1039/a804699i
Publication type
journal article
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