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Saturated and unsaturated triruthenium clusters containing three sterically demanding phosphine ligands : synthesis and structure of [Ru<sub>3</sub>(CO)<sub>9</sub>(PCy<sub>3</sub>)<sub>3</sub>] and [Ru<sub>3</sub>H<sub>2</sub>(CO)<sub>6</sub>(PCy<sub>3</sub>)<sub>3</sub>]
Auteur(s)
Godefroy, Isabelle
Ferrand, Vincent
Neels, Antonia
Date de parution
1998
In
Journal of the Chemical Society, Dalton Transactions, 1998//515-516
Résumé
The reaction of Na[Ru<sub>3</sub>H(CO)<sub>11</sub>] with an excess of tricyclohexylphosphine in methanol afforded, depending on the reaction conditions, the tri-substituted clusters [Ru<sub>3</sub>(CO)<sub>9</sub>(PCy<sub>3</sub>)<sub>3</sub>] (48e) and [Ru<sub>3</sub>H<sub>2</sub>(CO)<sub>6</sub>(PCy<sub>3</sub>)<sub>3</sub>] (44e), inaccessible hitherto.
Identifiants
Type de publication
journal article
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