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Half-sandwich trihydrido ruthenium complexes
Auteur(s)
Osipov, Alexandr L.
Gutsulyak, Dmitry V.
Kuzmina, Lyudmila G.
Howard, Judith A.K.
Lemenovskii, Dmitry A.
Nikonov, Georgii I.
Date de parution
2007
In
Journal of Organometallic Chemistry, Elsevier, 2007/692/22/5081-5085
Résumé
This paper reports facile preparation of half-sandwich trihydrido complexes of ruthenium based on the reactions of the readily available precursors [Cp(R<sub>3</sub>P)Ru(NCCH<sub>3</sub>)<sub>2</sub>][PF<sub>6</sub>] with LiAlH<sub>4</sub>. The target complexes were characterized by spectroscopic methods and X-ray structure analysis of Cp(PhPr<i><sup>i</i></sup><sub>2</sub><i>P</i>)RuH<sub>3</sub>.
Identifiants
Type de publication
journal article
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