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  4. Highly selective low-temperature hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol catalysed by hectorite-supported ruthenium nanoparticles
 
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Highly selective low-temperature hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol catalysed by hectorite-supported ruthenium nanoparticles

Auteur(s)
Khan, Farooq-Ahmad
Vallat, Armelle
Süss-Fink, Georg 
Institut de chimie 
Date de parution
2011
In
Catalysis Communications, Elsevier, 2011/12/15/1428–1431
Mots-clés
  • Ruthenium nanoparticles
  • Ruthenium-modified hectorite
  • Furfuryl alcohol hydrogenation
  • Ruthenium nanoparticl...

  • Ruthenium-modified he...

  • Furfuryl alcohol hydr...

Résumé
Metallic ruthenium nanoparticles intercalated in hectorite (particle size ~ 4 nm) were found to catalyse the hydrogenation of furfuryl acohol to give tetrahydrofurfuryl alcohol in methanolic solution under mild conditions. The best results were obtained at 40 °C under a hydrogen pressure of 20 bar (conversion 100%, selectivity > 99%). After a total turnover number of 1423, the hectorite supported ruthenium nanoparticles are deactivated but can be recycled and regenerated.
Identifiants
https://libra.unine.ch/handle/123456789/10066
_
10.1016/j.catcom.2011.05.024
Type de publication
journal article
Dossier(s) à télécharger
 main article: Khan_Farooq-Ahmad_-_Hihgly_selective_low-temperature_hydrogenation_20120606.pdf (2.61 MB)
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