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Half-sandwich trihydrido ruthenium complexes
Auteur(s)
Osipov, Alexandr L.
Gutsulyak, Dmitry V.
Kuzmina, Lyudmila G.
Howard, Judith A.K.
Lemenovskii, Dmitry A.
Nikonov, Georgii I.
Date Issued
2007
Journal
Journal of Organometallic Chemistry, Elsevier, 2007/692/22/5081-5085
Abstract
This paper reports facile preparation of half-sandwich trihydrido complexes of ruthenium based on the reactions of the readily available precursors [Cp(R<sub>3</sub>P)Ru(NCCH<sub>3</sub>)<sub>2</sub>][PF<sub>6</sub>] with LiAlH<sub>4</sub>. The target complexes were characterized by spectroscopic methods and X-ray structure analysis of Cp(PhPr<i><sup>i</i></sup><sub>2</sub><i>P</i>)RuH<sub>3</sub>.
Publication type
journal article
