Logo du site
  • English
  • Français
  • Se connecter
Logo du site
  • English
  • Français
  • Se connecter
  1. Accueil
  2. Université de Neuchâtel
  3. Publications
  4. Arene–ruthenium complexes with ferrocene-derived ligands: Synthesis and characterization of complexes of the type [Ru(η<sup>6</sup>-arene)(NC<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHOC-C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>)Cl<sub>2</sub>] and [Ru(η<sup>6</sup>-arene)(NC<sub>3</sub>H<sub>3</sub>N(CH<sub>2</sub>)<sub>2</sub>O<sub>2</sub>C–C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>)Cl<sub>2</sub>]
 
  • Details
Options
Vignette d'image

Arene–ruthenium complexes with ferrocene-derived ligands: Synthesis and characterization of complexes of the type [Ru(η<sup>6</sup>-arene)(NC<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHOC-C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>)Cl<sub>2</sub>] and [Ru(η<sup>6</sup>-arene)(NC<sub>3</sub>H<sub>3</sub>N(CH<sub>2</sub>)<sub>2</sub>O<sub>2</sub>C–C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>)Cl<sub>2</sub>]

Auteur(s)
Auzias, Mathieu
Editeur(s)
Gueniat, Joël
Therrien, Bruno 
Institut de chimie 
Süss-Fink, Georg 
Institut de chimie 
Renfrew, Anna K.
Dyson, Paul J.
Date de parution
2009
In
Journal of Organometallic Chemistry, Elsevier, 2009/694/6/855-861
Mots-clés
  • Ruthenium

  • Anticancer agents

  • Bioorganometallic che...

  • Arene ligands

  • Ferrocene-derived lig...

Résumé
Arene–ruthenium complexes of general formula [Ru(η<sup>6</sup>-arene)(L)Cl<sub>2</sub>] where L = NC<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHOC-C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>, arene = <i>p-<sup>i</sup></i>PrC<sub>6</sub>H<sub>4</sub>Me (<b>1</b>) or C<sub>6</sub>Me<sub>6</sub> (<b>2</b>); L = NC<sub>3</sub>H<sub>3</sub>N(CH<sub>2</sub>) <sub>2</sub>O<sub>2</sub>C–C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>, arene = <i>p-<sup>i</sup></i>PrC<sub>6</sub>H<sub>4</sub>Me (<b>3</b>) or C<sub>6</sub>Me<sub>6</sub> (<b>4</b>), and diruthenium–arene complexes of general formula [Ru(η<sup>6</sup>-arene)Cl<sub>2</sub>] <sub>2</sub> (L) where L = 1,1′-(NC<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHOC)<sub>2</sub>-C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>4</sub>, arene = <i>p-<sup>i</sup></i>PrC<sub>6</sub>H<sub>4</sub>Me (<b>5</b>) or C<sub>6</sub>Me<sub>6</sub> (<b>6</b>); L = 1,1′-(NC<sub>3</sub>H<sub>3</sub>N(CH<sub>2</sub>)<sub>2</sub>O<sub>2</sub>C)<sub>2</sub>–C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>4</sub>, arene = <i>p-<sup>i</sup></i>PrC<sub>6</sub>H<sub>4</sub>Me (<b>7</b>) or C<sub>6</sub>Me<sub>6</sub> (<b>8</b>) have been synthesized and characterized. The molecular structures of <b>1</b> and <b>3</b> were confirmed by single-crystal X-ray diffraction. The <i>in vitro</i> anticancer activities of complexes <b>1–8</b> have been studied comparatively to the uncoordinated ligands. The complexes exhibit fairly low cytotoxicities in comparison to related ferrocene-derived arene–ruthenium complexes.
URI
https://libra.unine.ch/handle/123456789/15693
DOI
10.1016/j.jorganchem.2008.08.012
Autre version
http://dx.doi.org/10.1016/j.jorganchem.2008.08.012
Type de publication
Resource Types::text::journal::journal article
Dossier(s) à télécharger
 main article: Auzias_Mathieu_-_Arene-ruthenium_complexes_with_ferrocene_20090319.pdf (715.49 KB)
google-scholar
Présentation du portailGuide d'utilisationStratégie Open AccessDirective Open Access La recherche à l'UniNE Open Access ORCID

Adresse:
UniNE, Service information scientifique & bibliothèques
Rue Emile-Argand 11
2000 Neuchâtel

Construit avec Logiciel DSpace-CRIS Maintenu et optimiser par 4Sciences

  • Paramètres des témoins de connexion
  • Politique de protection de la vie privée
  • Licence de l'utilisateur final