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  4. 1,4-Bis[4-(tert-butyl-diphenyl-silyl)buta-1,3-diyn-yl]benzene

1,4-Bis[4-(tert-butyl-diphenyl-silyl)buta-1,3-diyn-yl]benzene

Author(s)
Thevenet, Damien  
Laboratoire de biologie moléculaire et cellulaire  
Neier, Reinhard  
Institut de chimie  
Stoeckli-Evans, Helen  
Institut de chimie  
Date issued
2010
In
Acta Crystallogr Sect E Struct Rep Online
Vol
Pt 4
No
66
From page
o839
To page
40
Abstract
The title centrosymmetric mol-ecule, C(46)H(42)Si(2), is composed of a central benzene ring with buta-1,3-diynyl chains at positions 1 and 4. These chains are terminated by tert-butyl-diphenyl-silyl groups, hence the molecule is dumbbell in shape. The mol-ecules are connected via C-H(midline ellipsis)? inter-actions in the structure, so forming an undulating two-dimensional network in the bc plane. There is also a weak ?-? inter-action involving centrosymmetrically related phenyl rings with a centroid-centroid distance of 3.8359 (11) Å.
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/55046
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