Crystal structure of {N-[(2-hydroxyethylamino)ethylsalicylaldiminato]-palladium(II) chloride}: Synthesis, X-ray structure, electrochemistry, DFT and TDDFT studies
Author(s)
Ali Hasnaoui
Ismail Hdoufane
Rachid Idouhli
Mustapha Ait Al
Larbi El Firdoussi
Date issued
September 11, 2018
In
Journal of Molecular Structure
No
1176
From page
703
To page
710
Reviewed by peer
1
Subjects
Schiff base Palladium complex X-ray structure Electrochemistry DFT TDDF
Abstract
A new complex N-(2-hydroxyethylamino)ethylsalicylaldiminato]-palladium(II) chloride [Pd(L)Cl] was synthesized by the reaction in ethanol of the Schiff base 2-(2-(2-hydroxyethylamino)ethylimino)methyl phenol (LH) and Li2PdCl4. The complex was characterized by 1H NMR, 13C NMR, FT-IR and UVeVis spectroscopic techniques. The structure of the complex was confirmed by single-crystal X-ray structure analysis. The electrochemical properties of PdCl2 and [Pd(L)Cl] have been investigated by cyclic voltammetry. Additionally, the electronic structure, the solution spectrum and the redox property of [Pd(L)Cl] have been rationalized by DFT and TDDFT methods.
Publication type
journal article
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