Dibromodicarbonylbis(triphenylphosphine)ruthenium(II) dichloromethane solvate
Author(s)
Lozano Diz, Enrique
Neels, Antonia
Date issued
2002
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
8
No
58
From page
m404
To page
m405
Subjects
crystal structure ruthenium bromo carbonyl phenylphosphine chloromethane mol structure ruthenium bromo carbonyl phenylphosphine chloromethane
Abstract
The title mononuclear Ru compd. was prepd. by a new synthetic route and characterized by x-ray structure anal. Crystals are monoclinic, space group P21/n, with a 10.2056(6), b 40.436(3), c 10.3584(6) Å, ? 117.423(6)°; Z = 4, dc = 1.622; R = 0.038, Rw(F2) = 0.090 for 6181 reflections. As expected, the cis-Br2-cis-(CO)2-trans-(PPh3)2 configuration is obsd. around the metal. [on SciFinder(R)]
Publication type
journal article