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Dichlorido[1-(2-chloroethyl)-3-(pyridin-4-ylmethyl-?N)urea](?6-hexamethylbenzene)ruthenium(II) chloroform monosolvate
Auteur(s)
Date de parution
2011
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol.
11
No
67
Mots-clés
- mol structure ruthenium chlorido chloroethylpyridinylmethylurea hexamethylbenzene chloroform solvate
- crystal structure ruthenium chlorido chloroethylpyridinylmethylurea hexamethylbenzene chloroform solvate
- hydrogen bond ruthenium chlorido chloroethylpyridinylmethylurea hexamethylbenzene chloroform solvate
Résumé
The RuII atom in the title compd., [RuCl2(C12H18)(C9H12ClN3O)]·CHCl3, exhibits a typical piano-stool coordination, defined by a hexamethylbenzene ligand, two chloride ligands and a pyridylurea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is obsd. due to two strong N-H···Cl interactions between the NH groups of urea and the two chloride ligands of neighboring mols. The C=O group of the urea moiety interacts with the solvent mol. through weak C-H···O interactions. Crystallog. data and at. coordinates are given. [on SciFinder(R)]
Identifiants
Type de publication
journal article
