Dichlorido[1-(2-chloroethyl)-3-(pyridin-4-ylmethyl-?N)urea](?6-hexamethylbenzene)ruthenium(II) chloroform monosolvate
Author(s)
Date issued
2011
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
11
No
67
Subjects
mol structure ruthenium chlorido chloroethylpyridinylmethylurea hexamethylbenzene chloroform solvate crystal structure ruthenium chlorido chloroethylpyridinylmethylurea hexamethylbenzene chloroform solvate hydrogen bond ruthenium chlorido chloroethylpyridinylmethylurea hexamethylbenzene chloroform solvate
Abstract
The RuII atom in the title compd., [RuCl2(C12H18)(C9H12ClN3O)]·CHCl3, exhibits a typical piano-stool coordination, defined by a hexamethylbenzene ligand, two chloride ligands and a pyridylurea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is obsd. due to two strong N-H···Cl interactions between the NH groups of urea and the two chloride ligands of neighboring mols. The C=O group of the urea moiety interacts with the solvent mol. through weak C-H···O interactions. Crystallog. data and at. coordinates are given. [on SciFinder(R)]
Publication type
journal article