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The anion [(As5Mo4O20)-Mo-III-O-VI(OCH3)](2-): a new heteropolyoxometalate containing an unusual As5O4 chain
Auteur(s)
Laly, Myriam
Fidalgo, Eva Garcia
Date de parution
2002
In
Inorganic Chemistry Communications
Vol.
8
No
5
De la page
569
A la page
571
Résumé
The heteropolyoxometalate [(HAsAsMoMo8O34)-As-III-Mo-V-Mo-V-O-VI](6-) reacts in aqueous solution with an excess of sodium metaarsenite to give a new arsenomolybdate [(As5Mo4O20)-Mo-III-O-VI(OCH3)](2-) which crystallize as the tetrabutylammonium salt. The single-crystal X-ray structure analysis reveals a heteropolyoxometalate anion containing an unusual chain of five arsenic atoms linked to each other by bridging oxygen atoms. (C) 2002 Elsevier Science B.V. All rights reserved.
Identifiants
Type de publication
journal article
