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Coordination Assemblies from a Pd(II)-Cornered Square Complex
Auteur(s)
Date de parution
2005
In
Acc. Chem. Res.
Vol.
4
No
38
De la page
369
A la page
378
Résumé
A review. The [enPd(II)]2+ (en = ethylenediamine) unit has emerged as a versatile building block in mol. self-assembly. In particular, the 90° coordination angle of the metal was judiciously used in the design of new discrete two- and three-dimensional structures. The authors' last 15 years of work with the Pd(II)-cornered unit is summarized in this Account, from the spontaneous formation of a Pd4 square metal complex to a family of architectures such as cages, bowls, boxes, tubes, catenanes, and spheres. [on SciFinder(R)]
Identifiants
Type de publication
journal article
