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  4. 2-[2-(Pyrrolidin-2-yl)propan-2-yl]-1H-pyrrole and its amide derivative 1-{2-[2-(1H-pyrrol-2-yl)propan-2-yl]pyrrolidin-1-yl}ethanone
 
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2-[2-(Pyrrolidin-2-yl)propan-2-yl]-1H-pyrrole and its amide derivative 1-{2-[2-(1H-pyrrol-2-yl)propan-2-yl]pyrrolidin-1-yl}ethanone

Auteur(s)
Journot, Guillaume 
Institut de chimie 
Neier, Reinhard 
Institut de chimie 
Stoeckli-Evans, Helen 
Institut de physique 
Date de parution
2012
In
Acta Crystallogr., Sect. C Cryst. Struct. Commun.
Vol.
3
No
68
De la page
o119
A la page
o122
Mots-clés
  • Hydrogen bond (in propanepyrrole derivs.)
  • Crystal structure
  • Molecular structure (of propanepyrrole derivs.)
  • crystal mol structure hydrogen bond propanylpyrrole deriv
  • Hydrogen bond (in pro...

  • Crystal structure

  • Molecular structure (...

  • crystal mol structure...

Résumé
In the title compds., C11H18N2, (II), and C13H20N2O, (III), the pyrrolidine rings have twist conformations. Compd. (II) crystallizes with two independent mols. (A and B) in the asym. unit. The mean planes of the pyrrole and pyrrolidine rings are inclined to one another by 89.99 (11) and 89.35 (10)° in mols. A and B, resp. In (III), the amide deriv. of (II), the same dihedral angle is much smaller, at only 13.42 (10)°. In the crystal structure of (II), the individual mols. are linked via N-H···N hydrogen bonds to form inversion dimers, each with an R22(12) graph-set motif. In the crystal structure of (III), the mols. are linked via N-H···O hydrogen bonds to form inversion dimers with an R22(16) graph-set motif. [on SciFinder(R)]
Identifiants
https://libra.unine.ch/handle/123456789/21456
Type de publication
journal article
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