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cis-{trans-1,2-Bis[2-(diphenylphosphino)benzamido]cyclohexane-?2P,P'}dichloroplatinum(II) chloroform trisolvate
Auteur(s)
Date de parution
2004
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol.
8
No
60
De la page
m1163
A la page
m1165
Résumé
Crystals of the title compd. are monoclinic, space group P21/n, with a 19.3200(9), b 11.1284(4), c 25.6676(12) Å, ? 108.638(4)°; Z = 4, dc = 1.670; R = 0.036, Rw(F2) = 0.092 for 9068 reflections. The two P atoms in the square-planar complex adopt a cis configuration, forming a 13-membered metallacycle. The H atoms of the amide functions are oriented towards the Cl atoms, whereas the carbonyl groups interact with the solvent CHCl3 mols. by H bonds. [on SciFinder(R)]
Identifiants
Type de publication
journal article