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Dichlorido[1-(2-chloroethyl)-3-(pyridin-4-ylmethyl-<i>κ</i>N)urea](</i>η</i><sup>6</sup>-hexamethylbenzene)ruthenium(II) chloroform monosolvate
Auteur(s)
Date de parution
2011
In
Acta Crystallographica Section E : Structure Reports Online, Wiley, 2011/E67/11/m1613
Résumé
The Ru<sup>II</sup> atom in the title compound, [RuCl<sub>2</sub>(C<sub>12</sub>H<sub>18</sub>)(C<sub>9</sub>H<sub>12</sub>ClN<sub>3</sub>O)]•CHCl<sub>3</sub>, exhibits a typical piano-stool coordination, defined by a hexamethylbenzene ligand, two chloride ligands and a pyridylurea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is observed due to two strong N-H...Cl interactions between the NH groups of urea and the two chloride ligands of neighbouring molecules. In addition, the C=O group of the urea moiety interacts with the solvent molecule through weak C-H...O interactions.
Identifiants
Type de publication
journal article
