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4,4-Bis(1<i>H</i>-pyrrol-2-yl)pentanol
Date de parution
2010
In
Acta Crystallographica Section E : Structure Reports Online, International Union of Crystallography, 2010/E66/2/o393, sup1-8
Résumé
The title achiral compound, C<sub>13</sub>H<sub>18</sub>N<sub>2</sub>O, crystallized in the chiral monoclinic space group <i>P</i>2<sub>1</sub>. The pyrrole rings are inclined to one another by 62.30 (11)°, and the propanol chain is in an extended conformation. In the crystal, the two pyrrole NH groups are involved in intermolecular N-H ··· O hydrogen bonds, leading to the formation of a helical arrangement propagating along the <i>b</i> axis. An interesting feature of the crystal structure is the absence of any conventional hydrogen bonds involving the hydroxy H atom. There is, however, a weak intermolecular O-H ··· π interaction involving one of the pyrrole rings.
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Type de publication
journal article
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