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Application of the Novel Tandem Process <i>Diels-Alder</i> Reaction/<i>Ireland-Claisen</i> Rearrangement to the Synthesis of <i>rac</i>-Juvabione and <i>rac</i>-Epijuvabione
Auteur(s)
Soldermann, Nicolas
Velker, Joerg
Vallat, Olivier
Date de parution
2000
In
Helvetica Chimica Acta, Wiley, 2000/83/9/2266-2276
Résumé
The novel tandem process <i>Diels-Alder</i> reaction/<i>Ireland-Claisen</i> rearrangement shows a high diastereoselectivity for the <i>Ireland-Claisen</i> rearrangement starting from the <i>endo</i>-product of the <i>Diels-Alder</i> reaction. Based on this mechanistic knowledge, the novel tandem process could be applied to the synthesis of <i>rac</i>-juvabione.
Identifiants
Type de publication
journal article
