Thermodynamics of Mixtures. Excess Volumes and Energies of Mixing of Cycloalkane Mixtures (Cyclopentane to Cyclooctane)
Date de parution
Helvetica Chimica Acta, Wiley, 1973/56/7/2513-2516
The volumes of mixing for the systems cyclopentane + cyclohexane, cyclopentane + cycloheptane, cyclohexane + cycloheptane (at 20°C), and cyclopentane + cyclooctane, cyclohexane + cyclooctane, cycloheptane + cyclooctane (at 30 °C) have been measured with a dilatometer. All systems show volume contractions, except the first. The energies of mixing are also given. They vary from 7 to 55 J/mol for equimolar solutions.
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