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Synthesis and characterization of fullerene-pyridyl arene ruthenium complexes
Auteur(s)
In
Studia Universitatis Babes-Bolyai. Chemia, Universitatea din Cluj, 2015/60/4/229-238
Résumé
Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (<i>N</i><sub>pyr</sub>-C<sub>60</sub>) were synthesized <i>via</i> a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two half-sandwich complexes of the general formula (<i>p</i>-cymene)RuCl<sub>2</sub>(<i>N</i><sub>pyr</sub>-C<sub>60</sub>). The coordination of the fullerenopyrrolidines to the arene ruthenium unit was evidenced by NMR spectroscopy and mass spectrometry, thus confirming the formation of these novel arene ruthenium complexes.
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journal article
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