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Observation of the reversible H-induced structural transition in thin Y films via x-ray photoelectron diffraction
Auteur(s)
Hayoz, J.
Sarbach, S.
Pillo, Th.
Boschung, E.
Naumovic, D.
Aebi, Philipp
Schlapbach, Louis
Date Issued
1998
Journal
Physical Review B, American Physical Society (APS), 1998/58/8/R4270-R4273
Abstract
Yttrium can be loaded with hydrogen up to high concentrations causing dramatic structural and electronic changes of the host lattice. We report on the reversibility of hydrogen loading in thin single-crystalline Y films grown by vapor deposition on W(110). Under a H<sub>2</sub> partial pressure of 1×10<sup>-5</sup> mbar the hexagonal-closed- packed Y films convert to the face-centered-cubic Y dihydride. Unloading is accomplished by annealing the dihydride to 1000 K. No loss of crystallinity is observed during these martensitic transformations of the Y lattice. Moreover, we demonstrate a model to determine the H concentration in Y <i>in situ</i>.
Publication type
journal article
