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Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex
Auteur(s)
Date de parution
1999
In
Organometallics
Vol.
8
No
18
De la page
1565
A la page
1568
Mots-clés
Résumé
Anchoring a phosphine and an enantiopure camphorpyrazole tether to an arene (PArN*) yields, after ?6:?1:?1 coordination to ruthenium, [{?6:?1:?1-(PArN*)}RuL]2+ I as a 1:1 mixt. of diastereomers. These were sepd. and characterized by x-ray crystallog. The structure of the (R,RP,SRu)-I diastereomer is depicted. [on SciFinder(R)]
Type de publication
Resource Types::text::journal::journal article
