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Dibromodicarbonylbis(triphenylphosphine)ruthenium(II) dichloromethane solvate
Auteur(s)
Lozano Diz, Enrique
Neels, Antonia
Date de parution
2002
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol.
8
No
58
De la page
m404
A la page
m405
Résumé
The title mononuclear Ru compd. was prepd. by a new synthetic route and characterized by x-ray structure anal. Crystals are monoclinic, space group P21/n, with a 10.2056(6), b 40.436(3), c 10.3584(6) Å, ? 117.423(6)°; Z = 4, dc = 1.622; R = 0.038, Rw(F2) = 0.090 for 6181 reflections. As expected, the cis-Br2-cis-(CO)2-trans-(PPh3)2 configuration is obsd. around the metal. [on SciFinder(R)]
Identifiants
Type de publication
journal article