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Noble gases as tracers of surface water – groundwater interactions: insights from novel field and modelling approaches
Maison d'édition
Neuchâtel : Université de Neuchâtel
Date de parution
2023
Nombre de page
157
Mots-clés
- Alluvial aquifers
- Surface water – groundwater interactions
- Environmental tracers
- Artificial tracers
- Tracer injection
- Explicit tracer simulation
- Parameter estimation
- Integrated surface subsurface hydrological models
- Noble gases
- Radon-222
- Groundwater
- Groundwater age
- Data assimilation
- Mass transport
- Water resources management
Résumé
Understanding the interactions between surface water (SW) and groundwater (GW) in alluvial aquifer systems is of critical importance for the sustainable management of water resources. Advances in realtime and continuous measurement of a range of hydrological tracers provide new opportunities for the characterization of SW-GW dynamics at unprecedented spatiotemporal resolutions. Amongst several promising tracer methods, noble gases are particularly well-adapted to the study of SW-GW interactions, and provide an integrated signal on the flow paths and travel times of water. Capitalizing on the insights offered by novel measurement technologies requires tracer interpretation methods that appropriately capture tracer transport processes in dynamic environmental conditions. However, recourse to highly-simplified tracer interpretation methods, conceptually detached from the complexity of natural systems, is still widespread. In such cases, the potentially rich information content of tracer measurements may be underutilized.
This thesis aims at investigating how established and emerging noble gas tracer methods can be optimally used - and when they should be avoided - for the study of SW-GW interactions in alluvial aquifer systems. To this end, a range of novel laboratory, field, and modelling approaches are employed to systematically assess the applicability, limitations, and potential of some gas tracer methods toward informing SW-GW exchange processes. The first gas tracer method examined is the 222Rn apparent age model, which is widely used to estimate the ages of very young GW (days to weeks). High-resolution measurements of the spatial distribution of 222Rn emanation rates in an alluvial aquifer reveal significant spatial heterogeneity in 222Rn production. The explicit simulation of 222Rn in synthetic mass-transport models shows that this level of heterogeneity, combined with mixing of GW, can result in strongly biased estimates of GW age, effectively limiting the applicability of the 222Rn apparent age method to a limited range of field conditions. Although temporal changes in 222Rn concentrations may reveal insights into GW age dynamics, the information content of 222Rn measurements may be best extracted through the integration of 222Rn observations in the calibration process of physics-based flow and transport models.
Indeed, the second part of this thesis is devoted to exploring how the explicit simulation of tracer concentrations and the assimilation of untransformed tracer data in highly parameterized, physicsbased models may inform model parameters and ultimately predictions of management interest. Within this framework, the joint assimilation of hydraulic and noble gas data (222Rn and helium), acquired over the course of a novel tracer injection experiment, is shown to strongly inform model parameters and reduce predictive uncertainty of several important water management quantities, such as GW age, SW-GW mixing ratios, and SW infiltration fluxes, far beyond what is achieved with “traditional” hydraulic data alone. These results build upon mounting evidence as to the benefits of explicitly simulating and assimilating diverse observation types with physically-based flow and transport models, avoiding the layer of conceptual simplification and potential bias accrued with simplified tracer interpretation models.
Finally, the successful combination of novel gas injection methods, developed over the course of this project, and the assimilation of high-resolution gas tracer measurements in an explicit tracer simulation framework strongly support further developments of (noble) gas tracer methods and tracer-numerical model synergies.
This thesis aims at investigating how established and emerging noble gas tracer methods can be optimally used - and when they should be avoided - for the study of SW-GW interactions in alluvial aquifer systems. To this end, a range of novel laboratory, field, and modelling approaches are employed to systematically assess the applicability, limitations, and potential of some gas tracer methods toward informing SW-GW exchange processes. The first gas tracer method examined is the 222Rn apparent age model, which is widely used to estimate the ages of very young GW (days to weeks). High-resolution measurements of the spatial distribution of 222Rn emanation rates in an alluvial aquifer reveal significant spatial heterogeneity in 222Rn production. The explicit simulation of 222Rn in synthetic mass-transport models shows that this level of heterogeneity, combined with mixing of GW, can result in strongly biased estimates of GW age, effectively limiting the applicability of the 222Rn apparent age method to a limited range of field conditions. Although temporal changes in 222Rn concentrations may reveal insights into GW age dynamics, the information content of 222Rn measurements may be best extracted through the integration of 222Rn observations in the calibration process of physics-based flow and transport models.
Indeed, the second part of this thesis is devoted to exploring how the explicit simulation of tracer concentrations and the assimilation of untransformed tracer data in highly parameterized, physicsbased models may inform model parameters and ultimately predictions of management interest. Within this framework, the joint assimilation of hydraulic and noble gas data (222Rn and helium), acquired over the course of a novel tracer injection experiment, is shown to strongly inform model parameters and reduce predictive uncertainty of several important water management quantities, such as GW age, SW-GW mixing ratios, and SW infiltration fluxes, far beyond what is achieved with “traditional” hydraulic data alone. These results build upon mounting evidence as to the benefits of explicitly simulating and assimilating diverse observation types with physically-based flow and transport models, avoiding the layer of conceptual simplification and potential bias accrued with simplified tracer interpretation models.
Finally, the successful combination of novel gas injection methods, developed over the course of this project, and the assimilation of high-resolution gas tracer measurements in an explicit tracer simulation framework strongly support further developments of (noble) gas tracer methods and tracer-numerical model synergies.
Notes
Accepted on the recommendation of
Prof. Philip Brunner, University of Neuchâtel, Switzerland (Thesis director)
Prof. Daniel Hunkeler, University of Neuchâtel, Switzerland (Rapporteur)
Prof. Peter Cook, Flinders University, Australia (Rapporteur)
Prof. Olaf Cirpka, University of Tübingen, Germany (Rapporteur)
Dr. Roland Purtschert, University of Bern, Switzerland (Rapporteur)
Defended on May 17, 2023
Prof. Philip Brunner, University of Neuchâtel, Switzerland (Thesis director)
Prof. Daniel Hunkeler, University of Neuchâtel, Switzerland (Rapporteur)
Prof. Peter Cook, Flinders University, Australia (Rapporteur)
Prof. Olaf Cirpka, University of Tübingen, Germany (Rapporteur)
Dr. Roland Purtschert, University of Bern, Switzerland (Rapporteur)
Defended on May 17, 2023
Identifiants
Type de publication
doctoral thesis
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