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  • Publication
    Métadonnées seulement
    Mechanistic
    (2002)
    Laurenczy, Gábor
    ;
    Faure, Matthieu
    ;
    Vieille-Petit, Ludovic
    ;
    ;
    Ward, Thomas R
    In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)](+) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.
  • Publication
    Accès libre
    Mechanistic in situ High-Pressure NMR Studies of Benzene Hydrogenation by Supramolecular Cluster Catalysis with [(η6-C6H6)(η6-C6Me6)2Ru33-O)(μ2-OH)(μ2-H)2][BF4]
    (2002)
    Laurenczy, Gabor
    ;
    Faure, Matthieu
    ;
    Vieille-Petit, Ludovic
    ;
    ;
    Ward, Thomas R.
    In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(η6-C6H6)(η6-C6Me6)2Ru33-O)(μ2-OH)(μ2-H)2]+2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.