Options
Mechanistic
Auteur(s)
Laurenczy, Gábor
Faure, Matthieu
Vieille-Petit, Ludovic
Ward, Thomas R
Date de parution
2002
In
Advanced Synthesis & Catalysis
Vol.
10
No
344
De la page
1073
A la page
1077
Mots-clés
Résumé
In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)](+) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.
Identifiants
Type de publication
journal article
