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Pinault, Thomas
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Pinault, Thomas
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An iterative strategy for the synthesis of oligothiophenes by catalytic cross-coupling reactions
2004, Pinault, Thomas, Chérioux, Frédéric, Therrien, Bruno, Süss-Fink, Georg
An iterative strategy for the synthesis of new sulfur-functionalized oligothiophenes by Suzuki or Stille cross-coupling reactions was applied to the reaction of 4-bromo-tert-butylphenylthioether with thiophene derivatives. The planarity of the oligothiophenes obtained was confirmed by the single-crystal X-ray structure analysis of 2-(4-tert-butylthiophenyl)thiophene, which shows a potentially large electronic conjugation length.