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Deschenaux, Robert
Nom
Deschenaux, Robert
Affiliation principale
Fonction
Professeur.e ordinaire
Email
Robert.Deschenaux@unine.ch
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- PublicationAccès libreSynthesis and characterization of fullerene-pyridyl arene ruthenium complexes
;Appavoo, Divambal; Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (Npyr-C60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two half-sandwich complexes of the general formula (p-cymene)RuCl2(Npyr-C60). The coordination of the fullerenopyrrolidines to the arene ruthenium unit was evidenced by NMR spectroscopy and mass spectrometry, thus confirming the formation of these novel arene ruthenium complexes.