Cherry stones as precursor of activated carbons for supercapacitors
Author(s)
Olivares-Marín, M.
Fernández, J. A.
Lázaro, M. J.
Fernández-González, C.
Macías-García, A.
Gómez-Serrano, V.
Centeno, Teresa A.
Date issued
2009
In
Materials Chemistry and Physics, Elsevier, 2009/114/1/223-227
Subjects
microporous materials surfaces adsorption electrochemical properties
Abstract
It is shown that cherry stones-wastes can be recycled as activated carbons for electrode material in supercapacitors. KOH-activation of this precursor at 800–900 °C is an efficient process to obtain carbons with large specific surface areas (1100–1300 m<sup>2</sup> g<sup>−1</sup>), average pore sizes around 0.9–1.3 nm, which makes them accessible to electrolyte ions, and conductivities between 1 and 2 S cm<sup>−1</sup>. These features lead to capacitances at low current density as high as 230 F g<sup>−1</sup> in 2 M H<sub>2</sub>SO<sub>4</sub> aqueous electrolyte and 120 F g<sup>−1</sup> in the aprotic medium 1 M (C<sub>2</sub>H<sub>5</sub>)<sub>4</sub>NBF<sub>4</sub>/acetonitrile. Furthermore, high performance is also achieved at high current densities, which means that this type of materials competes well with commercial carbons used at present in supercapacitors.
Publication type
journal article
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