Application of the Novel Tandem Process <i>Diels-Alder</i> Reaction/<i>Ireland-Claisen</i> Rearrangement to the Synthesis of <i>rac</i>-Juvabione and <i>rac</i>-Epijuvabione

Author(s)
Soldermann, Nicolas
Velker, Joerg
Vallat, Olivier
Date issued
2000
In
Helvetica Chimica Acta, Wiley, 2000/83/9/2266-2276
Abstract
The novel tandem process <i>Diels-Alder</i> reaction/<i>Ireland-Claisen</i> rearrangement shows a high diastereoselectivity for the <i>Ireland-Claisen</i> rearrangement starting from the <i>endo</i>-product of the <i>Diels-Alder</i> reaction. Based on this mechanistic knowledge, the novel tandem process could be applied to the synthesis of <i>rac</i>-juvabione.
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/61156
DOI
10.1002/1522-2675(20000906)83:9<2266::AID-HLCA2266>3.0.CO
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