Elimination of sulfur from aromatic heterocycles by a water-soluble arene ruthenium cluster: synthesis and molecular structure of [H<sub>2</sub>S<sub>2</sub>Ru<sub>4</sub>(C<sub>6</sub>H<sub>6</sub>)<sub>4</sub>]Cl<sub>2</sub>

Author(s)
Chérioux, Frédéric
Date issued
2004
In
Chemical Communications, 2004//204-205
Abstract
C–S bond cleavage in thiophene, benzothiophene and dibenzothiophene is achieved under biphasic conditions by the water-soluble cluster cation [H<sub>4</sub>Ru<sub>4</sub>(C<sub>6</sub>H<sub>6</sub>)<sub>4</sub>]<sup>2+</sup> which is converted into the disulfido cluster [H<sub>2</sub>S<sub>2</sub>Ru<sub>4</sub>(C<sub>6</sub>H<sub>6</sub>)<sub>4</sub>]<sup>2+</sup>.
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/59025
DOI
10.1039/b310271h
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