Mechanistic <i>in situ</i> High-Pressure NMR Studies of Benzene Hydrogenation by Supramolecular Cluster Catalysis with [(η<sup>6</sup>-C<sub>6</sub>H<sub>6</sub>)(η<sup>6</sup>-C<sub>6</sub>Me<sub>6</sub>)<sub>2</sub>Ru<sub>3</sub>(μ<sub>3</sub>-O)(μ<sub>2</sub>-OH)(μ<sub>2</sub>-H)<sub>2</sub>][BF<sub>4</sub>]

Author(s)
Laurenczy, Gabor
Faure, Matthieu
Vieille-Petit, Ludovic
Ward, Thomas R.
Date issued
2002
In
Advanced Synthesis & Catalysis, 2002/344/1073-1077
Subjects
benzene hydrogenation biphasic conditions high-pressure NMR spectroscopy supramolecular cluster catalysis
Abstract
<i>In situ</i> high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(η<sup>6</sup>-C<sub>6</sub>H<sub>6</sub>)(η<sup>6</sup>-C<sub>6</sub>Me<sub>6</sub>)<sub>2</sub>Ru<sub>3</sub>(μ<sub>3</sub>-O)(μ<sub>2</sub>-OH)(μ<sub>2</sub>-H)<sub>2</sub>]<sup>+</sup><b>2</b>, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/58556
DOI
10.1002/1615-4169(200212)344:10%3C1073::AID-ADSC1073%3E3.0.CO%3B2-J
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