Saturated and unsaturated triruthenium clusters containing three sterically demanding phosphine ligands : synthesis and structure of [Ru3(CO)9(PCy3)3] and [Ru3H2(CO)6(PCy3)3]

Süss-Fink, Georg; Godefroy, Isabelle; Ferrand, Vincent; Neels, Antonia; Stoeckli-Evans, Helen

doi:10.1039/a708037i

Saturated and unsaturated triruthenium clusters containing three sterically demanding phosphine ligands : synthesis and structure of [Ru3(CO)9(PCy3)3] and [Ru3H2(CO)6(PCy3)3]

Author(s)

Süss-Fink, Georg

Institut de chimie

Godefroy, Isabelle

Ferrand, Vincent

Neels, Antonia

Stoeckli-Evans, Helen

Institut de chimie

Date issued

1998

In

Journal of the Chemical Society, Dalton Transactions, 1998//515-516

Abstract

The reaction of Na[Ru3H(CO)11] with an excess of tricyclohexylphosphine in methanol afforded, depending on the reaction conditions, the tri-substituted clusters [Ru3(CO)9(PCy3)3] (48e) and [Ru3H2(CO)6(PCy3)3] (44e), inaccessible hitherto.

Publication type

journal article

Identifiers

https://libra.unine.ch/handle/20.500.14713/58541

DOI

10.1039/a708037i

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1_S__ss-Fink_-_Saturated_and_unsaturated_triruthenium_20060910.pdf

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Saturated and unsaturated triruthenium clusters containing three sterically demanding phosphine ligands : synthesis and structure of [Ru<sub>3</sub>(CO)<sub>9</sub>(PCy<sub>3</sub>)<sub>3</sub>] and [Ru<sub>3</sub>H<sub>2</sub>(CO)<sub>6</sub>(PCy<sub>3</sub>)<sub>3</sub>]