[(eta(6)-p-Pr(i)C6H4Me)(2)Ru2Mo2O6(OMe)(4)]: a new tetranuclear mixed-metal oxo cluster presenting a cube-based chair structure
Author(s)
Date issued
1999
In
Inorganic Chemistry Communications
Vol
8
No
2
From page
344
To page
346
Subjects
crystal structures oxo clusters arene complexes ruthenium complexes molybdenum complexes AMPHIPHILIC ORGANORUTHENIUM OXOMOLYBDENUM X-RAY STRUCTURES CRYSTAL-STRUCTURES COMPLEXES DERIVATIVES OXOVANADIUM
Abstract
The title complex was obtained by reaction of [(eta(6)-p-Pr'C6H4Me)(4)Ru4Mo4O16] with methanol in the presence of p-hydroquinone. It contains an Mo2Ru2O2(OMe)(4) core consisting of two Mo2RuO(OMe)(3) half-cubes fused together to form a choir-like structure. (C) 1999 Elsevier Science S.A. All rights reserved.
Publication type
journal article