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  4. ?-Chloro-?-hydrido-bis[chloro(?6-p-cymene)ruthenium(II)](Ru-Ru): a second polymorph

?-Chloro-?-hydrido-bis[chloro(?6-p-cymene)ruthenium(II)](Ru-Ru): a second polymorph

Author(s)
Therrien, Bruno  
Institut de chimie  
Frein, Stephane
Süss-Fink, Georg  
Institut de chimie  
Date issued
2004
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
11
No
60
From page
m1666
To page
m1668
Subjects
crystal structure ruthenium chloro hydro cymene polymorph mol structure ruthenium chloro hydro cymene polymorph
Abstract
Crystals of the title complex are monoclinic, space group C2/c, with a 14.782(3), b 17.431(3), c 10.425(2) Å, ? 124.16(3)°; Z = 4, dc = 1.727; R = 0.022, Rw(F2) = 0.049 for 2163 reflections. The dinuclear complex has 2-fold symmetry. The terminal Cl atom interacts with three C-H H atoms of symmetry-related neighboring mols. These interactions play a key role in the packing arrangement. [on SciFinder(R)]
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/51343
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