The hydrogenation of heterocyclic calix[4]arenes, a transformation leading to novel macrocyclic ligands
Author(s)
Jones, Christopher R.
Blangy, Valeria
Date issued
2012
In
Heterocycles
Vol
4
No
85
From page
749
To page
797
Subjects
Porphyrins Role: SPN (Synthetic preparation) PREP (Preparation) (analogs review on hydrogenation of heterocyclic calixarenes leading to metal-binding macrocyclic ligands) Metacyclophanes Role: RCT (Reactant) SPN (Synthetic preparation) PREP (Preparation) RACT (Reactant or reagent) (calixarenes heterocyclic review on hydrogenation of heterocyclic calixarenes leading to metal-binding macrocyclic ligands) Heterocyclic compounds Role: RCT (Reactant) SPN (Synthetic preparation) PREP (Preparation) RACT (Reactant or reagent) (calixarenes review on hydrogenation of heterocyclic calixarenes leading to metal-binding macrocyclic ligands) Macrocyclic compounds Role: SPN (Synthetic preparation) PREP (Preparation) (ligands review on hydrogenation of heterocyclic calixarenes leading to metal-binding macrocyclic ligands) Ligands Role: SPN (Synthetic preparation) PREP (Preparation) (macrocyclic review on hydrogenation of heterocyclic calixarenes leading to metal-binding macrocyclic ligands) Complexation Hydrogenation (review on hydrogenation of heterocyclic calixarenes leading to metal-binding macrocyclic ligands) review heterocyclic calixarene hydrogenation calixpyrrolidine macrocyclic ligand prepn metal complexation review
Abstract
A review. Hydrogenation reactions of calix[4]furan and calix[4]pyrrole were reviewed together with the authors' own work in this field. A short description of the metal binding process of our new calix[4]pyrrolidines (= the fully satd. calix[4]pyrrole) with Cu was discussed as a typical example of the metal binding capacities. The new calix[4]pyrrolidines can be structurally classified as new stiffened macrocyclic crown ethers or as satd. analogs of the porphyrin-derived "pigments of life". [on SciFinder(R)]
Publication type
journal article