Sawhorse-type diruthenium tetracarbonyl complexes

Author(s)
Date issued
2009
In
Coordination Chemistry Reviews, Elsevier, 2009/253/21-22/2639-2664
Subjects
Ruthenium Carbonyl Sawhorse Carboxylato Carboxamido Amido Pyrazolato Triazenido Pyridonato Oximato Sulfonato Thiolato Selenolato Phosphato Phosphinato Phosphinito Phosphido
Abstract
The review covers dinuclear ruthenium complexes that contain a Ru<sub>2</sub>(CO)<sub>4</sub> backbone arranged in a typical sawhorse geometry as well as two three-electron bridges and two terminal two-electron ligands. Synthetic and structural aspects of these complexes are presented, and their catalytic and biological properties as well as their potential applications for nano-materials are reviewed.
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/58815
DOI
10.1016/j.ccr.2009.05.012
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