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Application of the novel tandem process Diels-Alder reaction/Ireland-Claisen rearrangement to the synthesis of rac-juvabione and rac-epijuvabione
Auteur(s)
Soldermann, Nicolas
Velker, Joerg
Vallat, Olivier
Date de parution
2000-1-12
In
Helvetica Chimica Acta
Vol.
9
No
83
De la page
2266
A la page
2276
Mots-clés
Résumé
The novel tandem process Diels-Alder reaction/Ireland-Claisen rearrangement shows a high diastereoselectivity for the Ireland-Claisen rearrangement starting from the endo-product of the Diels-Alder reaction. Based on this mechanistic knowledge, the novel tandem process could be applied to the synthesis of rac-juvabione.
Identifiants
Type de publication
journal article
