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An Efficient Photoinduced Deprotection of Aromatic Acetals and Ketals

Auteur(s)
Date de parution
2011
In
Helv. Chim. Acta
Vol.
2
No
94
De la page
331
A la page
346
Mots-clés
Résumé
A novel type of photodeprotection reaction of simple arom. acetals and ketals is described. The deprotection is highly efficient under optimized conditions. The arom. ring confers the photoreactivity to the compds. The efficiency of the process depends on the structure of the acetal moiety. The common minor side reaction, the photooxidn., becomes the major reaction pathway in the case of cyclic acetals. The use of photon as only reagent makes this procedure esp. attractive for acetal deprotection. [on SciFinder(R)]
Identifiants
https://libra.unine.ch/handle/123456789/21462
Type de publication
journal article