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  4. Di-μ-diphenylphosphido-bis{chlorido[(mesitylmethyl)diphenylphosphine-κP]palladium(II)}

Di-μ-diphenylphosphido-bis{chlorido[(mesitylmethyl)diphenylphosphine-κP]palladium(II)}

Author(s)
Chahen, Ludovic
Therrien, Bruno  
Institut de chimie  
Süss-Fink, Georg  
Institut de chimie  
Date issued
2007
In
Acta Crystallographica Section E, International Union of Crystallography, 2007/63/7/m1989
Abstract
In the title dinuclear palladium complex, [Pd<sub>2</sub> (C<sub>12</sub>H<sub>10</sub>P)<sub>2</sub>Cl<sub>2</sub> (C<sub>22</sub>H<sub>23</sub>P)<sub>2</sub>], the terminal ligands adopt a trans configuration with a Pd•••Pd distance of 3.6111 (4) Å. A crystallographic twofold rotation axis runs perpendicular to the Pd<sub>2</sub>P<sub>2</sub> ring. The Cl atom lies slightly out of the plane of the Pd and three P atoms in each half of the molecule.
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/58141
DOI
10.1107/S1600536807030280
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Chahen_Ludovic_-_Di-m-diphenylphosphido-bis_2009033.pdf

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