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  4. Reactivity of dinuclear arene ruthenium complexes: reactions of the hydrido complex [(p-Me-C6H4-Pr-i)(2)Ru2Cl2(mu-Cl)(mu-H)] with NaX and HX (X = F, Cl, Br, I)
 
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Reactivity of dinuclear arene ruthenium complexes: reactions of the hydrido complex [(p-Me-C6H4-Pr-i)(2)Ru2Cl2(mu-Cl)(mu-H)] with NaX and HX (X = F, Cl, Br, I)

Auteur(s)
Süss-Fink, Georg 
Institut de chimie 
Fidalgo, Eva Garcia
Neels, Antonia
Stoeckli-Evans, Helen 
Institut de physique 
Date de parution
2000
In
Journal of Organometallic Chemistry
Vol.
1-2
No
602
De la page
188
A la page
192
Mots-clés
  • rutherium complexes
  • hydrido complexes
  • arene complexes
  • HOMOGENEOUS HYDROGENATION CATALYST
  • CRYSTAL-STRUCTURE
  • AQUEOUS-SOLUTION
  • ACTIVATION
  • rutherium complexes

  • hydrido complexes

  • arene complexes

  • HOMOGENEOUS HYDROGENA...

  • CRYSTAL-STRUCTURE

  • AQUEOUS-SOLUTION

  • ACTIVATION

Résumé
The dinuclear hydride complex [(p-Me-C6H4-Pr')(2)Ru2Cl2(mu-Cl)(mu-H)] (1) reacts with the sodium halides NaX in methanol to give the halogen analogues [(p-Me-C6H4-Pr')(2)Ru2X2(mu-X)(mu-H)] (2: X = F, 3: X = Br, 4: X = I). With HX, complex 1 reacts to give the tetrahalo complexes [(p-Me-C6H4-Pr')(2)Ru2X2(mu-X)(2)] (5: X = Cl, 6: X = Br, 7: X = I); in the case of X = I, a large excess of HI leads to the formation of the cationic complex [(p-Me-C6H4-Pr')(2)Ru-2(mu-I)(3)](+) (8). The X-ray structure analysis of 1 shows a dinuclear Ru-2 backbone with two terminal chloro ligands being irans with respect to each other as the two p-cymene ligands, the two bridging ligands lie in a plane perpendicular to the plane defined by the terminal chloro ligands and the ruthenium atoms. (C) 2000 Elsevier Science S.A. All rights reserved.
Identifiants
https://libra.unine.ch/handle/123456789/13479
Type de publication
journal article
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