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[RuCl{2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine}(PPh3)2]BF4 dichloromethane solvate
Auteur(s)
Date de parution
2002
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol.
10
No
58
De la page
m557
A la page
m558
Résumé
The tetrafluoroborate salt of the mononuclear octahedral Ru(II) complex, [RuCl(L)(PPh3)2]BF4, where L = 2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine, was prepd. as the CH2Cl2 solvate. Crystals are triclinic, space group P?1, with a 10.3368(8), b 12.7939(11), c 19.1336(16) Å, ? 80.231(10), ? 89.193(9), ? 67.943(9)°; Z = 2, dc = 1.505; R = 0.031, Rw(F2) = 0.076 for 8322 reflections. The PPh3 ligands adopt a trans configuration, with a P-Ru-P angle of 173.72(2)°. [on SciFinder(R)]
Identifiants
Type de publication
journal article
