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Rac-(2R*,3R*)-S-Ethyl-4-Chloro-3-Hydroxy-2-Phenylbuthanethioate and Rac-(2R*,3R*)-S-Ethyl-2-Phenyl-3-(tosyloxy)buthanethioate: Dichotomy of the Stereoselectivity of the Mukaiyama Reaction
Chiral induction (Fel...
stereoselectivity dic...
3R*)-S-ethyl-4-chloro...
3R*)-S-ethyl-2-phenyl...
Ethers Role: PEP (Phy...
engineering or chemic...
RCT (Reactant)
PROC (Process)
RACT (Reactant or rea...
silyl
stereoselectivity dic...
3R*)-S-ethyl-4-chloro...
3R*)-S-ethyl-2-phenyl...
Dimers Role: FMU (For...
unclassified)
PEP (Physical
engineering or chemic...
PRP (Properties)
FORM (Formation
nonpreparative)
PROC (Process) (hydro...
stereoselectivity dic...
3R*)-S-ethyl-4-chloro...
3R*)-S-ethyl-2-phenyl...
Aldol addition (stere...
stereoselectivity dic...
3R*)-S-ethyl-4-chloro...
3R*)-S-ethyl-2-phenyl...
Chemical chains
Crystal structure
Hydrogen bond
Molecular structure
Mukaiyama aldol react...
Stereochemistry
Supramolecular struct...
Transition state stru...
3R*)-S-ethyl-4-chloro...
3R*)-S-ethyl-2-phenyl...
Hydrogen bond (weak
stereoselectivity dic...
3R*)-S-ethyl-4-chloro...
3R*)-S-ethyl-2-phenyl...
rac ethylchlorohydrox...