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  4. Lewis-Acid Catalyzed Tandem Reaction Diels-Alder-[3,3] Sigmatrophic Shift between Buta-1,3-Dienyl Thiocyanic Acid Ester and Acryloyl Chloride-Application in the Synthesis of 2-Azabicyclo[2.2.2]Oct-5-Ene Derivatives
 
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Lewis-Acid Catalyzed Tandem Reaction Diels-Alder-[3,3] Sigmatrophic Shift between Buta-1,3-Dienyl Thiocyanic Acid Ester and Acryloyl Chloride-Application in the Synthesis of 2-Azabicyclo[2.2.2]Oct-5-Ene Derivatives

Auteur(s)
Schoepfer, Joseph
Marquis, Christian
Pasquier, Cecile
Neier, Reinhard 
Institut de chimie 
Date de parution
1994
In
Journal of the Chemical Society-Chemical Communications
Vol.
8
De la page
1001
A la page
1002
Mots-clés
  • PALLADIUM
  • PALLADIUM

Résumé
Buta-1,3-dienyl thiocyanic acid ester reacts with acryloyl chloride in presence of Lewis acid catalysts to produce directly the rearranged product of type 3b via a combination of a Diels-Alder reaction with a [3,3] sigmatropic shift; the 1,4-substituted cyclohexene is easily transformed into the 2-azabicyclo[2.2.2]oct-5-ene derivative 6b, which has been used as precursor for the synthesis of the lbogamin skeleton.
Identifiants
https://libra.unine.ch/handle/123456789/6409
Type de publication
journal article
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