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rac-(Z)-Ethyl 2-bromo-2-[(3R,5R)-3-bromo-5-methyltetrahydrofuran-2-ylidene]acetate
Auteur(s)
Loiseau, Francois
Labat, Gael
Date de parution
2006
In
Acta Crystallogr., Sect. C Cryst. Struct. Commun.
Vol.
11
No
C62
De la page
o636
A la page
o638
Mots-clés
Résumé
In Et rac-(Z)-2-bromo-2-[(3R,5R)-3-bromo-5-methyltetrahydrofuran-2-ylidene]acetate, C9H12Br2O3, a (THF-2-ylidene)acetate, the double bond has the Z form. In the THF group, the relative configuration of the Br atom in the 3-position and the Me group in the 5-position is anti. The compd. crystallizes with 2 independent mols. per asym. unit and, in the crystal structure, the individual mols. are linked to their symmetry-equiv. mols. by C-H???O H bonds, so forming centrosym. H-bonded dimers. Crystallog. data are given. [on SciFinder(R)]
Identifiants
Type de publication
journal article