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Noble Metal Coordination Compounds Designed for Catalytic Organic Synthesis
Titre du projet
Noble Metal Coordination Compounds Designed for Catalytic Organic Synthesis
Description
The present research project focuses on the synthesis and structural characterization of new mono- and multinuclear organometallic complexes of ruthenium and palladium and on the study of their inherent catalytic potential for organic synthesis. Though being the cheapest of all noble metals, ruthenium and palladium have very promising catalytic features in particular for hydrogenation and for carbon-carbon coupling reactions. Within this project, we propose to work on three main topics which involve three Ph. D. students: Electron-Deficient Arene Ruthenium Clusters as highly selective olefin hydrogenation catalysts, Water-Soluble Organometallic Complexes as hydro¬genation or carbonylation catalysts in aqueous solution, and trans-Spanning Bi¬dentate Ligands for catalytic carbon-carbon and other coupling reactions.
Chercheur principal
Statut
Completed
Date de début
1 Octobre 2006
Date de fin
30 Septembre 2008
Organisations
Identifiant interne
32704
identifiant
Mots-clés
- SUPRAMOLECULAR CATALYSIS
- ORGANOMETALLIC CLUSTERS
- BIPHASIC REACTIONS
- HYDROGENATION
- CARBONYLATION
- HYDROFORMYLATION
- Ruthenium
- Palladium
- Mononuclear complexes
- Multinuclear complexes
- Electron-deficient clusters
- Catalysis
- Enantioselective reactions
- Water-soluble organometallics
- Trans-spanning bidentates
- Carbon-carbon coupling
SUPRAMOLECULAR CATALY...
ORGANOMETALLIC CLUSTE...
BIPHASIC REACTIONS
HYDROGENATION
CARBONYLATION
HYDROFORMYLATION
Ruthenium
Palladium
Mononuclear complexes...
Multinuclear complexe...
Electron-deficient cl...
Catalysis
Enantioselective reac...
Water-soluble organom...
Trans-spanning bident...
Carbon-carbon couplin...