Nanostructured Materials Containing Organoruthenium Clusters and Ruthenium Nanoparticles in Organized Organic Mesophases

Titre du projet

Description

The present research project focuses on the synthesis and characterization of new nanostructured materials based on organoruthenium clusters and on ruthenium nanoparticles with liquid-crystalline properties thanks to organized organic mesophases. Background Nanosized molecular materials, structured by self-organization, have raised much interest because of their unique properties and their potential applications. For such materials, functional qualities such as optoelectric, magnetic or catalytic properties can be introduced by transition metals, while the self-organization can be induced by mesogenic ligands. Aim We propose to synthesize nanostructured molecular architectures that contain dinuclear ruthenium cluster cores with dendritic side-chains as well as metallic ruthenium nanoparticles stabilized in nematic or smectic phases. We intend to study the mesophase transitions, the self-organisation phenomena as well as the optoelectric and catalytic properties of these new materials. Based on promising results obtained in the starting phase, this project intends to combine forces in the fields of organic synthesis, organometallic coordination and self-organization in order to design nanostructured molecules and mesogen-stabilized metallic nanoparticles that are mesomorphic and exhibit interesting physical properties. Significance This joint project in inorganic and organic chemistry, corresponding to a "bottom-up" approach to nanomaterials, reflects a strategic decision to orient the chemistry in Neuchâtel, on a long term basis, towards nanosciences and to intensify the interactions with microtechnology.

Chercheur principal

Süss-Fink, Georg

Deschenaux, Robert

Statut

Completed

Date de début

1 Avril 2009

Date de fin

30 Septembre 2011

Chercheurs

Gras, Michael

Khan, Farooq-Ahmad