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Therrien, Bruno

Nom
Therrien, Bruno
Affiliation principale
Fonction
Professeur titulaire
Email
bruno.therrien@unine.ch
Identifiants
https://libra.unine.ch/handle/123456789/382
_
0000-0002-0388-2745

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  • Publication
    Accès libre
    Combining coordination and hydrogen-bonds to form arene ruthenium metalla-assemblies
    Appavoo, Divembal
    ;
    Carnevale, Diego
    ;
    Deschenaux, Robert 
    ;
    Therrien, Bruno 
    Three ureido-pyrimidone derivatives (N-LH) were used to generate in combination with four dinuclear arene ruthenium clips, (p-cymene) 2Ru2(OO boolean AND OO)Cl2 (OO boolean AND OO = oxalato, 2,5-dioxido-1,4-benzoquinonato, 2,5-dichloro-1,4-benzoquinonato, 5,8-dioxido-1,4-naphtoquinonato), twelve cationic arene ruthenium metalla-cycles of the general formula [(p-cymene)2Ru2(OO boolean AND OO)(N-LH)2]2 (CF3SO3)4. The ureidopyrimidone moieties are able to form strong hydrogen-bonds by self-pairing, thus giving rise to dimeric structures in solution. In addition, to better understand the behavior of the tetranuclear metallacycles in solution, the neutral dinuclear arene ruthenium ureido-pyrimidone complexes of the general formula ((p-cymene)RuCl2(N-LH)} 2 were also prepared and characterized. All metalla-assemblies were studied in solution by NMR spectroscopy, confirming the high stability of the metalla- cycles and the usefulness of hydrogen-bonds in constructing supramolecular assemblies